5. Paul Polman, Unilever
Paul Polman, Unilever
Unliver CEO Paul Polman wasn't yet an internationally known CEO when he climbed Mount Kilimanjaro in 2005. He ascended the peak with a friend who had been the only blind person to climb Mount Everest, and his experience led him to create the Kilimanjaro Blind Trust, a charity benefiting blind children in Africa.

The cause remains close to his heart as the hearty 55-year-old climber continues to lead the Dutch consumer giant that owns Ben & Jerry's ice cream, Dove, and Hellman's.

Last updated July 12 2011: 5:15 PM ET
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Fortune 500's baller and shot caller CEOs

These CEOs may not have made it to the major leagues as athletes, but they did exhibit sports prowess at the high school and collegiate level.