Company: Campbell Soup
Fortune 500 rank: 312
First year as CEO: 2011
Most Powerful Women rank: 21
This rookie CEO worked at a slew of consumer goods companies (P&G, Kraft, Pepsi, Nabisco, Nestlé) and served as Campbell's operating chief before ascending to the top of the $7.7-billion-in-revenue company in August. MPW fact: Morrison and Maggie Wilderotter are the first sister act to make the list.
NEXT: Deanna Mulligan